Dr. Gourab MukherjeeA. Jalila SimaanJagnyesh Kumar SatpathyApparao DraksharapuDyuti BhandarySk AmanullahDivya Lakshmi Hareendran2026-08-162026-08-162026-07Mukherjee, G., Satpathy, J. K., Bhandary, D., Hareendran, D. L., Draksharapu, A., Sk, A., & Simaan, A. J. (2026). Generation and reactivity of a mononuclear copper(III)-azide complex stable at room temperature. Chemical Communications. https://doi.org/10.1039/D6CC03266D10.1039/d6cc03266dhttps://ir.chanakyauniversity.edu.in/handle/123456789/216Herein, we report a room temperature stable terminal Cu(III)-azide complex supported by a strong ligand field with bis-amido and pyridine-based r-donors in a protected coordination environment. This Cu(III)-species can be generated both chemically and electrochemically and shows electrophilic reactivity towards O–H, C–H activation, and azidation reactions.enCopper(III) complexesCopper–azide complexesMononuclear copper complexesCopper azideMetal–azide chemistryjournal-article